Temazepam
7-chloro-3-hydroxy-1-methyl-5-phenyl-3H-1,4-benzodiazepin-2-one
Overview
Temazepam belongs to Depressants / Benzodiazepines.
Effects
- Drowsiness, calm and easier sleep onset and maintenance, coming on within about half an hour.
- Impaired coordination, concentration and short-term memory (anterograde amnesia), dizziness, and next-morning grogginess.
- With regular use: tolerance, dependence, and rebound insomnia/anxiety and other withdrawal symptoms on stopping.
Dosing & duration
Oral (hard capsules/tablets and soft-gelatin capsules), prescribed and dose-adjusted by a clinician. Figures are therapeutic (prescribing) context, not a recreational guide.. Temazepam is a prescription hypnotic for short-term use (typically 2–4 weeks including taper). The lowest effective dose is taken shortly before bed, with reduced doses in the elderly and debilitated. It should not be combined with alcohol, opioids or other sedatives, and next-day driving may be impaired.
Dose ranges
10–20 mg at bedtime (occasionally up to 30 mg)
7.5–10 mg at bedtime
Duration
≈20–30 min
Up to ≈8 h
Possible next-morning drowsiness. Rebound insomnia on stopping
Chemical & Physical Properties
| Formula | C16H13ClN2O2 |
| Molar mass | 300.74 g/mol |
| State | Solid (white crystalline powder) |
| Melting point | 119–121 °C |
| Boiling point | Not reported |
| Density | Not reported |
| Vapor pressure | Not reported |
| pKa | Not reported |
| LogP | 2.19 |
| Solubility | 164 mg/L, 5.34×10⁻² g/L |
| Refractive index | Not reported |
Identifiers & Synonyms
| CAS | 846-50-4 |
| CAS (enantiomer) | |
| PubChem CID | 5391 |
| InChIKey | SEQDDYPDSLOBDC-UHFFFAOYSA-N |
| InChI | InChI=1S/C16H13ClN2O2/c1-19-13-8-7-11(17)9-12(13)14(18-15(20)16(19)21)10-5-3-2-4-6-10/h2-9,15,20H,1H3 |
| SMILES | CN1C2=C(C=C(C=C2)Cl)C(=NC(C1=O)O)C3=CC=CC=C3 |
Synonyms
- Restoril
- Normison
- Euhypnos
- Jellies
Pharmacodynamics & Biochemistry
Temazepam (Restoril, Normison, Euhypnos) is an intermediate-acting benzodiazepine used chiefly as a hypnotic for insomnia. Like the rest of the class it is a positive allosteric modulator at the benzodiazepine site of the GABA-A receptor (the α/γ2 subunit interface): in the presence of GABA it increases the frequency of chloride-channel opening, enhancing inhibitory neurotransmission to produce sedation, hypnosis, anxiolysis, muscle relaxation and anticonvulsant effects. Structurally it is the 3-hydroxy, N-methyl analogue of oxazepam, and it is itself one of the pharmacologically active metabolites of diazepam. Its metabolism resembles oxazepam's more than that of the long-acting benzodiazepines: temazepam is cleared largely by direct glucuronidation of its 3-hydroxyl group to an inactive O-glucuronide (about 90%), with only minor N-demethylation to oxazepam, and it forms no long-lived active metabolites. This gives it an intermediate elimination half-life of roughly 8–20 hours and a hypnotic duration of up to about 8 hours, long enough to maintain sleep but short enough to limit next-day accumulation, and, like the other conjugated benzodiazepines, it is comparatively well tolerated in the elderly and in hepatic impairment. Oral bioavailability is high (about 96%). Hypnotic effects begin in under 30 minutes and peak plasma levels are reached at roughly 2–3 hours, faster for the soft-gelatin/liquid-filled formulations than for hard capsules. Temazepam has a single chiral centre at C3 and is used as the racemate, as with oxazepam its enantiomers interconvert (racemise) readily in solution, so a single-enantiomer preparation offers no advantage: the existing (R)/(S) depiction is kept without a principal-form badge. Its benzodiazepine-site affinity is high but is not separately curated with a clean quantitative constant in the major binding databases, so it is described here qualitatively rather than with a receptor-binding table.
Biological targets
- GABA-A
Binding & functional measurements
| Target | Measurement | Species |
|---|---|---|
| GABA-A α1β2γ2 receptor | EC50 4.0 nM | Human |
Pharmacokinetics
| Bioavailability | Oral ~96% |
| Tmax | ≈2–3 h (faster for soft-gel/liquid-filled capsules) |
| Half-life | ≈8–20 h (intermediate) |
| Vd | Not reported |
| Protein binding | Not reported |
| Metabolism | Direct hepatic glucuronidation of the 3-OH to an inactive O-glucuronide (~90%). Minor N-demethylation to oxazepam. No active metabolites |
| Excretion | Renal (mainly as the glucuronide) |
Toxicology & Safety
Not reported
Temazepam is an intermediate-acting hypnotic benzodiazepine and carries the class's core risks. It causes dose-dependent sedation, next-morning drowsiness, dizziness, impaired coordination, concentration and short-term memory (anterograde amnesia), so it impairs driving and increases fall risk, particularly in the elderly. Like all benzodiazepines it produces tolerance, physical dependence and, on stopping after regular use, a withdrawal syndrome (rebound insomnia and anxiety, tremor, sweating and, after high-dose or abrupt cessation, seizures), so courses are kept short (typically 2–4 weeks including a taper). It can cause respiratory depression, which becomes dangerous, and is a leading mechanism of benzodiazepine-related death, when combined with opioids, alcohol or other CNS depressants. Historically, the gel-filled capsules (street names 'jellies', 'eggs') were heated and injected by drug users, causing serious harm including limb ischaemia, gangrene and abscesses. This prompted reformulation and the tighter UK Schedule 3 control. Because it is cleared mainly by direct conjugation rather than oxidation, it has fewer pharmacokinetic drug interactions than most benzodiazepines and is comparatively safer in liver disease and old age. Use cautiously in sleep apnoea, severe respiratory insufficiency, myasthenia gravis, a history of substance misuse, and in pregnancy.[2]
Legal Status
US: Schedule IV. UK: Class C (Schedule 3). DE: BtMG Anlage III
Interactions & Contraindications
Drug interactions
Contraindications
No interactions or contraindications listed.
Usage & Context
- A prescription hypnotic for the short-term treatment of severe or debilitating insomnia, taken shortly before bed to shorten sleep latency and improve sleep maintenance.
- Favoured where a benzodiazepine hypnotic is wanted without the day-after accumulation of long-acting agents, and, like oxazepam and lorazepam, usable in the elderly and in hepatic impairment because its direct-conjugation metabolism produces no active metabolites.
- Also a pharmacologically active metabolite of diazepam, and misused recreationally (historically including hazardous injection of the gel-capsule formulations).
Sources & Evidence
- PubChem: Temazepam (CID 5391) — identifiers & experimental properties
- Wikipedia: Temazepam (Restoril) — GABA-A benzodiazepine-site PAM, glucuronidation metabolism (no active metabolites), racemate, uses, adverse effects & legal status CC BY-SA 4.0
- DEA Diversion Control Division: Controlled Substance Schedules (temazepam is Schedule IV)
- GOV.UK: Controlled drugs list — temazepam is Class C / Schedule 3 (Misuse of Drugs legislation) OGL v3.0
- Norman C, Liin SI, Jauregi-Miguel A, Ottosson NE, Gréen H (2026). In vitro γ-aminobutyric acid A (GABAA) receptor activity and binding interactions at the α+/γ2− interface of 53 prescription and designer benzodiazepines. Commun Chem 9:155.
PMID 41946818 · doi:10.1038/s42004-026-02001-x