Oxycodone
(5R,9R,13S,14S)-4,5α-epoxy-14-hydroxy-3-methoxy-17-methylmorphinan-6-one
Overview
Oxycodone belongs to Opioids.
Effects
- Pain relief with a warm relaxation and, especially at higher or non-oral doses, euphoria and calm detachment. Drowsiness and clouded thinking.
- Physical signs: pinpoint pupils, slowed breathing, itch, nausea/vomiting and constipation.
- With regular use: tolerance to the euphoria and analgesia (but not to constipation), physical dependence, and an unpleasant flu-like withdrawal on stopping.
Dosing & duration
Oral (immediate- and controlled-release), and by injection (IV/IM/subcutaneous): clinician-prescribed and titrated. Figures below are clinical context, NOT a recreational guide.. Oxycodone is a prescription strong opioid. Dosing is individualised and titrated to effect and tolerance, with very different doses in opioid-naïve versus opioid-tolerant patients. There is no safe recreational dose: the amount that produces euphoria in a naïve person overlaps with the amount that stops their breathing, and the danger multiplies with any other depressant. Controlled-release tablets must be swallowed whole: crushing them to snort or inject releases the full dose at once and frequently kills. Oral oxycodone is roughly 1.5× as potent as oral morphine. Have naloxone available. Never use alone.
Dose ranges
≈5–15 mg every 4–6 h, titrated
≈10 mg every 12 h, swallowed whole, titrated
Oral oxycodone ≈ 1.5× oral morphine
Duration
IR ≈10–30 min, oral ≈30–60 min
IR analgesia ≈4–6 h (controlled-release ≈12 h)
Sedation/constipation may persist. Withdrawal on cessation after regular use
Chemical & Physical Properties
| Formula | C18H21NO4 |
| Molar mass | 315.36 g/mol |
| State | Solid |
| Melting point | 219 °C |
| Boiling point | Not reported |
| Density | Not reported |
| Vapor pressure | Not reported |
| pKa | 8.53 |
| LogP | 0.7 |
| Solubility | 166mg/mL, Insoluble in water, Nearly insoluble in water |
| Refractive index | Not reported |
Identifiers & Synonyms
| CAS | 76-42-6 |
| CAS (enantiomer) | |
| PubChem CID | 5284603 |
| InChIKey | BRUQQQPBMZOVGD-XFKAJCMBSA-N |
| InChI | InChI=1S/C18H21NO4/c1-19-8-7-17-14-10-3-4-12(22-2)15(14)23-16(17)11(20)5-6-18(17,21)13(19)9-10/h3-4,13,16,21H,5-9H2,1-2H3/t13-,16+,17+,18-/m1/s1 |
| SMILES | CN1CC[C@]23[C@@H]4C(=O)CC[C@]2([C@H]1CC5=C3C(=C(C=C5)OC)O4)O |
Synonyms
- OxyContin
- Oxycodone
- Roxicodone
- Dihydrohydroxycodeinone
- Oxy
- Percs
Pharmacodynamics & Biochemistry
Oxycodone is a semi-synthetic opioid made from thebaine (a poppy alkaloid). It is an agonist at the μ-opioid receptor (MOR), with much weaker activity at the κ- and δ-opioid receptors. Like other opioids it acts through Gi/Go signalling to reduce neuronal excitability and neurotransmitter release along pain pathways, producing analgesia together with euphoria, sedation, pinpoint pupils, cough suppression, constipation and, the dangerous effect, depression of the brainstem respiratory drive (reversible by naloxone). It is itself an active opioid of moderate MOR affinity. Clinically it is somewhat more potent than oral morphine (roughly 1.5×), helped by a high oral bioavailability (~60–90%) and good CNS penetration. It is metabolised in the liver by CYP2D6 to oxymorphone (a much more potent MOR agonist, usually a minor contributor to the overall effect) and by CYP3A4 to noroxycodone (weakly active), because of the CYP2D6 and CYP3A4 routes, genetic variation and interacting drugs can meaningfully change its effect. At the receptor level it binds the μ-opioid receptor with Kᵢ ≈18 nM and far more weakly at the δ (≈958 nM) and κ (≈677 nM) receptors. Oxycodone became central to the prescription-opioid crisis: aggressive marketing of the controlled-release product OxyContin from the late 1990s, and the crushing of those tablets to defeat the slow-release and snort or inject the full dose, drove widespread dependence, overdose and a later shift to heroin and illicit fentanyl.
Biological targets
- MOR
Binding & functional measurements
| Target | Measurement | Species |
|---|---|---|
| KOR | pKi 6.17 | |
| DOR | pKi 6.02 | |
| μ-opioid receptor | Ki 26 nM | Human |
Pharmacokinetics
| Bioavailability | Oral ≈60–87% |
| Tmax | Immediate-release ≈1–1.5 h |
| Half-life | ≈3–5 h |
| Vd | ≈2.6 L/kg |
| Protein binding | ≈45% |
| Metabolism | Hepatic CYP3A4 to noroxycodone and CYP2D6 to active oxymorphone |
| Excretion | Renal |
Toxicology & Safety
Not reported
Oxycodone is a strong opioid and its central danger is dose-dependent respiratory depression, the usual mechanism of opioid death, which is greatest in opioid-naïve people, at higher doses, and above all when it is combined with other CNS depressants (benzodiazepines, alcohol, gabapentinoids, other opioids), a combination that carries an FDA boxed warning. Overdose (pinpoint pupils, unconsciousness, slow or absent breathing) is a medical emergency reversible with naloxone. It has a high abuse and dependence potential: with repeated use, tolerance and physical dependence develop, and stopping abruptly causes an opioid withdrawal syndrome (agitation, aches, sweating, gastrointestinal upset, craving). Crushing or dissolving controlled-release tablets to snort or inject them delivers the whole dose at once and is a frequent cause of fatal overdose, as is co-use with alcohol or benzodiazepines. Constipation, nausea, sedation and itch are common. Risk is higher in the elderly, in respiratory disease, and with CYP2D6/CYP3A4-interacting drugs. It should not be used with MAOIs. Never use non-medically alone. Have naloxone available.[4][3]
Legal Status
US: Schedule II. UK: Class A. DE: BtMG Anlage III
Interactions & Contraindications
Drug interactions
Contraindications
No interactions or contraindications listed.
Usage & Context
- A widely used strong opioid analgesic for moderate-to-severe acute pain (after surgery or injury), cancer pain and palliative care: given as immediate-release tablets/liquid and as 12-hourly controlled-release tablets (OxyContin), sometimes combined with paracetamol or naloxone.
- Also heavily misused: it is one of the opioids most associated with the prescription-opioid epidemic, diverted and taken orally, insufflated or injected for euphoria.
- Sold under many names (OxyContin, Roxicodone, Percocet with paracetamol) and known on the street as 'oxy' or 'percs'.
Sources & Evidence
- Volpe DA, McMahon Tobin GA, Mellon RD, et al. (2011). Uniform assessment and ranking of opioid μ receptor binding constants for selected opioid drugs. Regul Toxicol Pharmacol 59:385-90.
PMID 21215785 · doi:10.1016/j.yrtph.2010.12.007
- PubChem: Oxycodone (CID 5284603) — identifiers & experimental properties
- FDA / DailyMed: Oxycodone prescribing information — pharmacokinetics & metabolism
- Kalso E (2005). Oxycodone. J Pain Symptom Manage 29:S47-56.
PMID 15907646 · doi:10.1016/j.jpainsymman.2005.01.010
- Wikipedia: Oxycodone — μ-opioid pharmacology, metabolism, OxyContin/opioid-crisis history, effects, dependence & legal status CC BY-SA 4.0
- DEA Diversion Control Division: Controlled Substance Schedules (oxycodone is Schedule II)
- GOV.UK: Controlled drugs list — oxycodone is Class A / Schedule 2 (Misuse of Drugs legislation) OGL v3.0