Lorazepam
7-chloro-5-(2-chlorophenyl)-3-hydroxy-1,3-dihydro-2H-1,4-benzodiazepin-2-one
Overview
Lorazepam belongs to Depressants / Benzodiazepines.
Effects
- Calming and relief of anxiety, drowsiness and sedation, muscle relaxation and, at higher doses, sleep. A sense of emotional 'blunting' is common.
- Anterograde amnesia (difficulty forming new memories), impaired coordination and balance, dizziness, slurred speech and slowed reaction time are typical, especially early in treatment or at higher doses.
- Tolerance to the sedative and hypnotic effects and physical dependence develop with continued use. Paradoxical reactions (agitation, irritability, disinhibition) occur in a minority, and a 'hangover' of grogginess can follow.
Dosing & duration
Oral tablets (0.5, 1, 2 mg) and oral solution. Also given intramuscularly and intravenously in hospital settings. Prescription-only. The figures below are medical reference ranges from the drug label and StatPearls, not recreational guidance. Lorazepam is potent and its effects are strongly amplified by alcohol and other CNS depressants, and it must never be combined with opioids. Oral use for anxiety is meant to be short-term (the FDA advises against use beyond about four weeks). Doses are individualised and must be tapered slowly, never stopped abruptly, after regular use.
Dose ranges
0.5–1 mg two to three times daily, increase as needed to a maximum of 10 mg/day in divided doses
2–4 mg at bedtime
0.1 mg/kg (maximum 4 mg per dose)
0.05 mg/kg ~2 h before surgery (maximum 4 mg)
Duration
Oral ~20–30 min, IV 1–5 min, IM 15–30 min
Intermediate-acting: clinical effect ~6–8 h (elimination half-life ≈10–20 h)
Residual drowsiness, grogginess and impaired coordination or memory. Rebound anxiety or insomnia after regular use
Chemical & Physical Properties
| Formula | C15H10Cl2N2O2 |
| Molar mass | 321.16 g/mol |
| State | Solid |
| Melting point | 166–168 °C |
| Boiling point | unavailable: true. reason: the only figure available is a software prediction (~534 °C at 1 atm), which is not physically meaningful: lorazepam is a crystalline solid that thermally decomposes well before boiling, so no reliable experimental boiling point exists |
| Density | Not reported |
| Vapor pressure | Not reported |
| pKa | 13 |
| LogP | 2.39 |
| Solubility | 80 mg/L, 1.76×10⁻² g/L |
| Refractive index | Not reported |
Identifiers & Synonyms
| CAS | 846-49-1 |
| CAS (enantiomer) | |
| PubChem CID | 3958 |
| InChIKey | DIWRORZWFLOCLC-UHFFFAOYSA-N |
| InChI | InChI=1S/C15H10Cl2N2O2/c16-8-5-6-12-10(7-8)13(19-15(21)14(20)18-12)9-3-1-2-4-11(9)17/h1-7,15,21H,(H,18,20) |
| SMILES | C1=CC=C(C(=C1)C2=NC(C(=O)NC3=C2C=C(C=C3)Cl)O)Cl |
Synonyms
- Ativan
- Temesta
- Lorazepam
- Tavor
Pharmacodynamics & Biochemistry
Lorazepam is a high-potency, intermediate-acting benzodiazepine. It binds the benzodiazepine site of the GABA-A receptor, the interface between an α (α1/α2/α3/α5) subunit and the γ2 subunit, and acts as a positive allosteric modulator: it does not open the channel itself but increases the frequency with which the endogenous transmitter GABA opens the chloride channel. The greater chloride influx hyperpolarises the neuron and dampens its firing, producing anxiolytic, sedative, hypnotic, anticonvulsant, muscle-relaxant and amnesic effects. It is a high-affinity (low-nanomolar), non-subtype-selective agonist that binds α1-, α2-, α3- and α5-containing receptors with broadly similar affinity, which is why it produces the full range of benzodiazepine effects rather than a subtype-selective one. No cleanly curated per-subtype binding constants are catalogued for it in the major open pharmacology databases, so a quantitative binding table is deliberately not shown. Compared with diazepam it is considerably less lipid-soluble, so it enters the brain a little more slowly but also redistributes out of it less. This gives lorazepam a longer duration of central action than its serum half-life alone would suggest, and is a reason intravenous lorazepam is a preferred first-line drug for status epilepticus. In-vitro receptor screening also identifies lorazepam as a positive allosteric modulator of the proton-sensing receptor GPR68, and reports only very weak, clinically irrelevant activity at an α1B-adrenoceptor (Ki ≈ 160 µM). Neither is thought to contribute to its clinical effects, which are GABAergic.
Biological targets
- GABA-A
Binding & functional measurements
| Target | Measurement | Species |
|---|---|---|
| GABA-A α1β2γ2 receptor | EC50 5.0 nM | Human |
Pharmacokinetics
| Bioavailability | Oral ≈90% |
| Tmax | ≈2 h |
| Half-life | ≈10–20 h |
| Vd | Not reported |
| Protein binding | ≈85% |
| Metabolism | Hepatic glucuronidation (no active metabolites, CYP-independent) |
| Excretion | Renal |
Toxicology & Safety
Not reported
Lorazepam's main dangers are dependence and dangerous combinations. Physical dependence and a withdrawal syndrome develop in a substantial minority of people treated for more than a few weeks, and because lorazepam is relatively short-acting the withdrawal can be brisk and severe, rebound anxiety and insomnia, tremor, and in serious cases seizures and psychosis, so it must be tapered slowly and never stopped abruptly after regular use. Its abuse and dependence liability is high for a benzodiazepine. The gravest acute risk is additive central-nervous-system and respiratory depression when it is combined with opioids (the subject of an FDA boxed warning), alcohol, or other sedatives: a leading cause of benzodiazepine-related overdose deaths. It commonly causes drowsiness, dizziness and marked anterograde amnesia (pronounced relative to other benzodiazepines), impairs coordination and driving, and raises the risk of falls and hip fractures in older adults. Paradoxical excitement, agitation or disinhibition occur in a minority. Use in late pregnancy can cause neonatal sedation and withdrawal ('floppy infant syndrome').[3][4]
Legal Status
US: Schedule IV. UK: Class C. DE: BtMG Anlage III
Interactions & Contraindications
Drug interactions
Contraindications
No interactions or contraindications listed.
Usage & Context
- A prescription benzodiazepine (Ativan, Tavor, Temesta) for the short-term relief of anxiety and anxiety-related insomnia, and as premedication before surgery or procedures for its sedative and amnesic effects.
- Intravenous lorazepam is a first-line treatment for status epilepticus, and it is widely used for alcohol-withdrawal syndrome, acute agitation, catatonia and chemotherapy-related anticipatory nausea.
- Like other benzodiazepines it is also misused recreationally and to 'come down' from stimulants. Its high potency and dependence liability make non-medical use and long-term daily use particularly risky.
Sources & Evidence
- PubChem: Lorazepam (CID 3958) — identifiers & computed properties
- FDA / DailyMed: Lorazepam prescribing information — pharmacokinetics & metabolism
- Ghiasi N, Bhansali RK, Marwaha R. Lorazepam. StatPearls [Internet] (NCBI Bookshelf, NBK532890) — mechanism, indications, dosing, adverse effects & interactions
- Wikipedia: Lorazepam (pharmacology, pharmacokinetics, adverse effects & legal status) CC BY-SA 4.0
- IUPHAR/BPS Guide to PHARMACOLOGY: lorazepam (ligand 5884) — screening data (GPR68 positive allosteric modulator, weak α1B-adrenoceptor) CC BY-SA 4.0
- DEA Diversion Control Division: Controlled Substance Schedules (lorazepam is Schedule IV)
- GOV.UK: Controlled drugs list — lorazepam is Class C (Misuse of Drugs Act 1971) OGL v3.0
- Anlage III BtMG — Betäubungsmittelgesetz (Gesetze im Internet): Lorazepam, mit Ausnahme niedrig dosierter Zubereitungen (bis 2,5 mg je abgeteilter Form)
- Arendt RM, Greenblatt DJ, Liebisch DC, et al. (1987). Determinants of benzodiazepine brain uptake: lipophilicity versus binding affinity. Psychopharmacology (Berl) 93:72-6.
PMID 2888155 · doi:10.1007/BF02439589
- Norman C, Liin SI, Jauregi-Miguel A, Ottosson NE, Gréen H (2026). In vitro γ-aminobutyric acid A (GABAA) receptor activity and binding interactions at the α+/γ2− interface of 53 prescription and designer benzodiazepines. Commun Chem 9:155.
PMID 41946818 · doi:10.1038/s42004-026-02001-x