Dimenhydrinate (Dramamine)
2-benzhydryloxy-N,N-dimethylethanamine;8-chloro-1,3-dimethyl-7H-purine-2,6-dione
Overview
Dimenhydrinate (Dramamine) belongs to Deliriants.
Effects
Dosing & duration
Not reported
Dose ranges
Duration
Chemical & Physical Properties
| Formula | C24H28ClN5O3 |
| Molar mass | 469.96 g/mol |
| State | Solid |
| Melting point | 102–107 °C |
| Boiling point | Not reported |
| Density | Not reported |
| Vapor pressure | Not reported |
| pKa | Not reported |
| LogP | Not reported |
| Solubility | Slightly soluble (1–10 mg/mL at 22 °C) (NTP, 1992), 3000 mg/L, Freely soluble in alcohol and chloroform. Soluble in benzene. Water solubility about 3 mg/mL. Almost insoluble in ether |
| Refractive index | Not reported |
Identifiers & Synonyms
| CAS | Not reported |
| CAS (enantiomer) | |
| PubChem CID | 10660 |
| InChIKey | NFLLKCVHYJRNRH-UHFFFAOYSA-N |
| InChI | InChI=1S/C17H21NO.C7H7ClN4O2/c1-18(2)13-14-19-17(15-9-5-3-6-10-15)16-11-7-4-8-12-16;1-11-4-3(9-6(8)10-4)5(13)12(2)7(11)14/h3-12,17H,13-14H2,1-2H3;1-2H3,(H,9,10) |
| SMILES | CN1C2=C(C(=O)N(C1=O)C)NC(=N2)Cl.CN(C)CCOC(C1=CC=CC=C1)C2=CC=CC=C2 |
Synonyms
- Dramamine
- Vomex
Pharmacodynamics & Biochemistry
Dimenhydrinate is not a single molecule but a 1:1 salt of two components: diphenhydramine (a first-generation antihistamine) and 8-chlorotheophylline (a xanthine related to caffeine). Diphenhydramine is the pharmacologically dominant part. The 8-chlorotheophylline is added mainly to offset its drowsiness by contributing a mild stimulant effect. Diphenhydramine is a lipophilic ethanolamine H1-antihistamine that acts as an inverse agonist / competitive antagonist at histamine H1 receptors. Because it readily crosses the blood–brain barrier, central H1 blockade produces the sedation and much of the antiemetic and anti-vertigo action for which dimenhydrinate is used: chiefly by damping signalling from the vestibular system and the vomiting centre. It also has marked antimuscarinic (anticholinergic) activity, blocking muscarinic acetylcholine receptors. This adds to the anti-motion-sickness effect but also causes the typical anticholinergic side-effects, dry mouth, blurred vision, urinary retention and constipation, and, in overdose, an anticholinergic delirium (agitation, hallucinations, mydriasis, flushing, hyperthermia, tachycardia) that underlies its recreational 'deliriant' misuse. At toxic concentrations diphenhydramine also blocks cardiac sodium and potassium channels, which can cause QRS widening, QT prolongation and arrhythmias, while the 8-chlorotheophylline component adds a stimulant load. Elimination is hepatic.
Biological targets
- H1
- mAChR
Binding & functional measurements
Pharmacokinetics
| Bioavailability | Not reported |
| Tmax | Not reported |
| Half-life | Several hours |
| Vd | Not reported |
| Protein binding | Not reported |
| Metabolism | Hepatic |
| Excretion | Not reported |
Toxicology & Safety
Not reported
At high exposure can cause anticholinergic delirium and cardiotoxicity (sodium/potassium-channel block → QRS/QT prolongation and arrhythmias). Additive sedation with alcohol and other CNS depressants. Anticholinergic burden is dangerous in the elderly and in children. Recreational high-dose use for its deliriant effect is associated with severe, unpleasant toxicity and hospitalisation.
Legal Status
US: Over-the-counter. UK: Pharmacy/OTC. DE: Pharmacy only (OTC)
Interactions & Contraindications
Drug interactions
Contraindications
No interactions or contraindications listed.
Usage & Context
- Therapeutic.